Second life batteries: The challenges

Now that we understand the need of giving EV batteries a second life, let’s check where is the problem, because there is always a problem, otherwise, what engineers are for?

The first and main problem is that the cells that are manufactured for the EVs are different from the ones manufactured for the stationary storage systems.

The EV market needs high energy density, batteries capable of fast charging and absorbing high power demands. Cycles are not that important, because the battery capacity is bigger than the daily needs of most drivers. Those cells are usually with nickel-rich cathodes.

On the other hand, in ESS we need high number of cycles and we don’t care that much about energy density, since space is not that critical. What we want is a low cost per number of cycles, so the investment makes sense. Have in mind, that a typical installation is a PV+ESS for home applications, where the battery will have a full daily cycle. In addition, we don’t need that high C-rate.

Ok, an extra stop here, what is the C-rate of a battery?

It’s a unit to measure the speed at which a battery is charged or discharged. 1C means that the battery is charged/discharged in 1 hour. 2C is in 30 minutes. C/2 is 2 hours. C/20, 20 hours.

Now that we understand what a C-rate is, we can conclude that the EV needs to be charged very fast, so we need high C-rates, like 5C (12 minutes) or 2C (30 minutes), but when we are charging the battery in our home from PV, we usually have 3 to 5 hours to charge it, which means C/3 or C/5, a much lower C-rate.

In conclusion, if we use cells that are manufactured for high C-rates, we will have less cycles, and that is not what we want in stationary applications.

To solve this issue, we will have to oversize the system. How?

Imagine that you need a battery that gives you 10 kWh each day. If you buy a new LFP battery, you will probably use it between it’s 10% SoC and 90% SoC, so you will have to buy a battery of 12.5 kWh.

10% State of Charge means that the battery has 10% of its total capacity available: 1.25 kWh

90% State of Charge means that the battery has 90% of its total capacity available: 11.25 kWh

Therefore, you are using 11.25 kWh – 1.25 kWh = 10 kWh

This new battery, designed for stationary applications, will provide you around 5000 cycles. A cycle per day, you will have this battery for 13 years.

But if you are going to use a second-life battery, you shouldn’t get to such low SoCs like 10%, because the deeper you discharge the battery (lower SoC), the less number of cycle you would get.

If we have less number of cycles, let’s say 3000 cycles for a new EV battery, to reach a similar number of cycles you will need to stay in a minimum SoC of 50% or 60%. Which means that you have to oversize the battery.

If you still need to use 10 kWh and your SoC will be moving between 90% and 50%, the second-life battery will have to be of 25 kWh. You can do the math as in the previous case with the new battery.

That is the double. A second-life battery of 25 kWh and a new battery of 12.5 kWh will provide you with the same service. If the new battery costs 250 USD/kWh, the second-life battery should cost 125 USD/kWh to be competitive.

Those numbers are very approximate and not precise. The objective is to provide you with a sense of scale. In the next articles, I will publish more specific cases with more detailed simulations. Inshallah.

Other challenges

The real life cycle

The current estimation of the end of life of a new battery in the EV market is when the SoH reaches 70%-80% or the internal resistance is double [1]. But most probably, this threshold of SoH will be lower with time, since we will discover that the batteries are able to survive longer periods, they might even be able to outlive the car itself. You can check more info in this article [2].

EV batteries having longer life in an EV than reused in the stationary market is a downside for the business model of the second-life batteries, because the remaining SoH will be lower the moment that you will refurbish them.

Future prices

Let’s assume that an EV battery costs 150 USD/kWh to manufacture today and it is sold at 250 USD/kWh. In 10 years, the battery might cost 100 USD/kWh to manufacture and will be sold for 200 USD/kWh. Let’s assume that the same battery that is manufactured today will be sold again to a second-life batteries manufacturer in 10 years. It will be sold at least at 150 USD/kWh to cover the cost. Therefore, you will have to sell it at 180 USD/kWh, to be competitive. But what about the additional cost of refurbishment? The margin for a competitive business model is risky.

Refurbishment cost

When a second-life battery manufacturer receives the original pack from an OEM, the battery can be kept in the same case, analyzed and installed in a bigger system or it can be opened, and the different modules taken. The modules could also be opened and the cells taken.

If you reach the cells or modules level, you will be able to group different cells/modules with different levels of degradation. Separating the cells will be better than the modules, because the module might have a degraded cell that could affect the remaining cells. But that is a lot of work, which will increase the final price.

If we keep the battery pack as it is from the start, the cost will be much more competitive, but the chance of a faster degradation of the whole pack is higher.

From the Automotive Cells Co

Warranty

The second-life batteries are usually bought from the OEMs, but the original cell manufacturer, will no longer cover the retired battery with warranties and will refuse any liability. This will be an additional cost in hands of the second-life battery manufacturer.

The used-car market

In the article [3], they notice that in 2021, the most sold EV cars in Germany was Tesla Model 3 and VW Up. Tesla Model 3 has a range of more than 500 km (bigger battery) and VW Up is half of that, 250 km (smaller battery).

That means that the market has two types of customers, people that they understand that 250 km is enough for their need and people that they prefer the security of the 500 km. When the battery of the Tesla Model 3 will reach its end of life, it might be able to provide 250 km instead of 500. It is possible that someone will like to buy that car, since we can see that the range reduction wouldn’t be an issue for a buyer.

In this way, the used-car market will be a competitor to the second-life manufacturers, reducing the available batteries for repurposing.

Homogeneity

The previous topics are critical issues that must be addressed. In addition, just in case you are not depressed yet, the business model is built on a very manual labor, since there is no chance for now to process the refurbishment in an automatic manner. In addition, the batteries among manufacturers, even between models of the same manufacturer, are very different, so it requires adapting the refurbishment process every time. In other words, there is a lack of homogeneity.

Conclusion

I know this article was a bit depressing, and second-life batteries business model looks unviable. But that is not true. In the next article, I will try to share with you some of the current solutions to all these challenges. Remember what I said in the beginning, engineers are here to solve these challenges. I am just building a dramatic context for a happy Hollywood ending.

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Notes

[1] U. ABC, ‘US ABC Electric Vehicle Battery Test Procedures Manual, Revision 2,’ principal author: Gary Hunt, Idaho National Engineering Laboratory, US Dept of Energy Idaho Field Office.

[2] https://www.forbes.com/sites/carltonreid/2022/08/01/electric-car-batteries-lasting-longer-than-predicted-delays-recycling-programs/

[3] https://doi.org/10.1016/j.xcrp.2022.101095